Automated Determination of Ammonium at Nanomolar Levels in Seawater by Coupling Lab-in-Syringe with Highly Sensitive Light-Emitting-Diode-Induced Fluorescence Detection.

ABSTRACT: Ammonium concentrations in marine environments are typically found at the nanomolar level, and due to the transformation tendencies of ammonium species, there is a growing demand for a simple, convenient, and highly sensitive automated method for seawater ammonium quantification. Such a method should be suitable for in situ applications without the need for additional enrichment or extraction steps. To meet this need, we developed a highly sensitive automated flow system that integrates a portable LED-induced fluorescence detector, incorporating the novel AccuOpt 2000 photodetector and lab-in-syringe technology, enabling direct fluorescence measurement of trace ammonium in seawater. Key system parameters were optimized, and the seawater matrix effects were assessed. The system achie

SUBMITTER: Guo X 

PROVIDER: S-EPMC11945248 | biostudies-literature | 2025 Mar

REPOSITORIES: biostudies-literature