Dual Visible and NIR Emission, Mechanoluminescence, and Magnetic Properties of PPh₄[<i>Ln</i>L₄] Chelates with Diphenyl-N-Benzoylamidophosphate.

ABSTRACT: The design, synthesis, and study of lanthanide coordination compounds with luminescent and magnetic properties attractive in modern technologies is still a pressing and challenging task. In the present work, a series of coordination compounds of tetrakis-carbacylamidophosphate PPh₄[LnL₄] (where HL = diphenyl-N-benzoylamidophosphate) with several lanthanide ions such as Nd^III, Sm^III, Dy^III, and Tm^III was prepared and studied by X-ray analysis and luminescence spectroscopy at 293 and 77 K, as well as by magnetic measurements. Coordination compounds are not isostructural, but the type of coordination is the same. All of them have intense sensitized emission. PPh₄[Sm

SUBMITTER: Kariaka N 

PROVIDER: S-EPMC11946015 | biostudies-literature | 2025 Mar

REPOSITORIES: biostudies-literature