Ternary surface complexation promotes simultaneous removal of arsenic and uranium by TiO₂.

ABSTRACT: The co-occurrence of arsenic and uranium in groundwater has been found in many countries, posing a significant challenge to human health. Here, we have demonstrated the efficient simultaneous removal of arsenic and uranyl-carbonate complexes from groundwater using {001}-TiO₂. Surprisingly, the presence of U(VI) greatly enhanced the adsorption of As(V) on {001}-TiO₂, while As(V) had a negligible impact on U(VI) adsorption. Through in situ ATR-FTIR spectroscopy, we uncovered a mechanism involving the formation of a ternary surface complex [Ti-U(VI)-As(V)] on the surface of {001}-TiO₂. This ternary surface complex formed through the substitution of CO₃^2- from uranyl coordination sites. Furthermore, the adsorbed As(V) and U(VI) can be easi

SUBMITTER: Lin L 

PROVIDER: S-EPMC11962437 | biostudies-literature | 2025 Mar

REPOSITORIES: biostudies-literature