Unsymmetric Ir<sub>2</sub> and RhIr Dinuclear Complexes Supported by a Linear Tetraphosphine <i>meso</i>-dpmppp, Showing High Reactivity for O<sub>2</sub>, H<sub>2</sub>, and HCl.
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ABSTRACT: Unsymmetric dinuclear Ir(I) complexes, [Ir2Cl2(L)(meso-dpmppp)] (L = XylNC (1aIr2), tBuNC (1bIr2), CO (1cIr2)), were synthesized using meso-Ph2PCH2P(Ph)(CH2)3P(Ph)CH2PPh2 (meso-dpmppp), which supports cis-P,P (M1) and trans-P,P (M2) metal sites, and exhibited high reactivity for O2, H2, and HCl. The IrRh heterodinuclear complexes, [M1M2Cl2(L)(meso-dpmppp)] (1xM1M2) (M1M2 = IrRh, RhIr; L = XylNC, C
SUBMITTER: Nakajima T
PROVIDER: S-EPMC11962856 | biostudies-literature | 2024 Oct
REPOSITORIES: biostudies-literature
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