Single-Wavelength Visible-Light-Induced Reversible Isomerization of Stiff-Stilbene under Dynamic Covalent Control.

ABSTRACT: Formylation of stiff-stilbene enables isomerization by visible instead of UV light, as is monitored by UV-vis and ¹H NMR spectroscopy. Further, it allows dynamic covalent imine formation, which gives rise to slightly blue-shifted absorbance. As a result, the irradiation wavelength that is used to promote E → Z isomerization for the formylated species, causes the opposite Z → E isomerization for the imine derivative. This feature can be used to produce either isomer with the same light source under control of imine formation and hydrolysis. Single crystal X-ray analysis and TD-DFT calculations provide structural and electronic insight.

SUBMITTER: Bekaert IM 

PROVIDER: S-EPMC11998061 | biostudies-literature | 2025 Apr

REPOSITORIES: biostudies-literature