Transformation of 3D Metal-Organic Frameworks into Nanosheets with Enhanced Memristive Behavior for Electronic Data Processing.

ABSTRACT: The transition from three-dimensional (3D) to two-dimensional (2D) semiconducting and insulating materials for micro- and opto-electronics is driven by an energy efficiency and device miniaturization. Herein, the simplicity of growth and stacking of 2D metal-organic framework (MOF) with such planar devices opens up new perspectives in controlling their efficiency and operating parameters. Here, the study reports on 3D to 2D MOF' structural transformation to achieve ultrathin nanosheets with enhanced insulating properties. Based on neutral N-donor ligands, the study designs and solvothermally synthesizes 3D MOFs followed by their thermal and solvent treatment to implement the transformation. A set of single crystal and powder X-ray diffraction, electron microscopy, Raman spectroscopy, numer

SUBMITTER: Mezenov YA 

PROVIDER: S-EPMC12021068 | biostudies-literature | 2025 Apr

REPOSITORIES: biostudies-literature