Large Hyperfine Coupling Arising from Pseudo-²S Ground States in a Series of Lutetium(II) Metallocene Complexes.

ABSTRACT: The synthesis of molecules with strong coupling between electronic and nuclear spins represents an important challenge in molecular quantum information science. Here, we report the synthesis and characterization of the divalent lutetium metallocene complexes Lu(Cp^Me₅)(Cp^iPr₅) (Cp^Me₅ = pentamethylcyclopentadienyl; Cp^iPr₅ = pentaisopropylcyclopentadienyl), Lu(Cp^iPr₄Et)₂ (Cp^iPr₄Et = ethyltetraisopropylcyclopentadienyl), and Lu(Cp^iPr₄)₂ (Cp^iPr₄ = tetraisopropylcyclopentadienyl). The molecular structures of these complexes, as

SUBMITTER: Ngo DX 

PROVIDER: S-EPMC12023037 | biostudies-literature | 2025 Apr

REPOSITORIES: biostudies-literature