In Situ Generated Sulfate-Facilitated Efficient Nitrate Electrosynthesis on 2D PdS₂ with Unique Imitating Growth Feature.

ABSTRACT: As a green sustainable alternative technology, synthesizing nitrate by electrocatalytic nitrogen oxidation reaction (NOR) can replace the traditional energy-intensive Ostwald process. But low nitrogen fixation yields and poor selectivity due to the high bond energy of the N≡N bond and competition from the oxygen evolution reaction in the electrolyte restrict its application. On the other hand, two-dimensional (2D) PdS₂ as a member in the family of group-10 novel transition metal dichalcogenides (NTMDs) presents the interesting optical and electronic properties due to its novel folded pentagonal structure, but few researches involve to its fabrication and application. Herein, unique imitating growth feature for PdS₂ on different 2D substrates has been firstly discovere

SUBMITTER: Zhang R 

PROVIDER: S-EPMC12158905 | biostudies-literature | 2025 Jun

REPOSITORIES: biostudies-literature