Hydrolysis-Engineered Robust Porous Micron Silicon Anode for High-Energy Lithium-Ion Batteries.

ABSTRACT: Micro-silicon (Si) anode that features high theoretical capacity and fine tap density is ideal for energy-dense lithium-ion batteries. However, the substantial localized mechanical strain caused by the large volume expansion often results in electrode disintegration and capacity loss. Herein, a microporous Si anode with the SiO_x/C layer functionalized all-surface and high tap density (~ 0.65 g cm⁻³) is developed by the hydrolysis-driven strategy that avoids the common use of corrosive etchants and toxic siloxane reagents. The functionalized inner pore with superior structural stability can effectively alleviate the volume change and enhance the electrolyte contact. Simultaneously, the outer particle surface forms a continuous network that prevents electrolyte parasiti

SUBMITTER: Liu M 

PROVIDER: S-EPMC12165945 | biostudies-literature | 2025 Jun

REPOSITORIES: biostudies-literature