Extrinsic gating of the rotary direction of a light-driven molecular motor by dynamic boronic acid-diol complexation.

ABSTRACT: Chiral sterically overcrowded alkenes are potential candidates for artificial light-driven rotary molecular motors (LRMMs), which perform a full 360° unidirectional rotation around the C[double bond, length as m-dash]C bond through a series of photochemical and thermal isomerization processes. However, the majority of the reported LRMMs adopt an intrinsic chirality (i.e., an integration of the chirality center with the photoresponsive unit), which hampers the effective gating of their rotary direction through chirality switching. Herein, we report a new sterically overcrowded alkene equipped with a boronic acid receptor for dynamic covalent bonding with chiral vicinal diols, enabling it to function as an extrinsic chirality-based LRMM. The dynamic boronic acid-chiral diol B-O bondin

SUBMITTER: Chen ZJ 

PROVIDER: S-EPMC12247126 | biostudies-literature | 2025 Aug

REPOSITORIES: biostudies-literature