Mechanochemical Synthesis and Electron Crystallography Characterization of van der Waals Lanthanoid 2D Metal-Organic Frameworks.

ABSTRACT: Mechanochemical synthesis provides access to clean, effective, and rapid synthesis of 2D van der Waals MOFs [Ln(MeCOO)(PhCOO)₂] (1Eu, 2Eu, 2Tb). The method also allows easy access to heterometallic analogue 2LaTb. All samples are obtained as nanosized crystals, and 1Eu has been characterized by electron crystallography (3D-ED). Thus, mechanochemistry and 3D-ED is a winning combination for the clean synthesis of 2D MOFs that can be upscaled to multigram synthesis.

SUBMITTER: Lorenzo F 

PROVIDER: S-EPMC12265042 | biostudies-literature | 2025 Jul

REPOSITORIES: biostudies-literature