Dynamic nuclear polarization with trityl radicals.

ABSTRACT: Despite the expanding applications of dynamic nuclear polarization (DNP) to problems in biological and materials science, there remain unresolved questions concerning DNP mechanisms. In this paper, we investigate the Zeeman DNP frequency profiles obtained with trityl radicals, OX063 and its partially deuterated analog OX071, in two commonly used glassing matrices based on glycerol and dimethyl sulfoxide (DMSO). When microwave irradiation is applied in the neighborhood of the narrow EPR transition, we observe a dispersive shape in the ¹H Zeeman field and the effects are larger in DMSO than in glycerol. With the help of direct DNP observations on ¹³C and ²H nuclei, we investigate the origin of this dispersive field profile. In particular, we observe a weak nu

SUBMITTER: Shankar Palani R 

PROVIDER: S-EPMC12279392 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature