Liquid Coordination Polymers with Anhydrous Proton Conductivity.

ABSTRACT: Liquid states in coordination polymers (CPs) and metal-organic frameworks (MOFs) are typically considered transient intermediates in the crystal-to-glass transformations of organic-inorganic hybrid materials. However, their potential as functional materials has remained largely unexplored. Inspired by the unique properties of ionic liquids, organic liquids, and liquid metals, we explore liquid CPs as a platform for novel functionalities distinct from those of their crystalline and glass counterparts. Here, we present a strategy to achieve functional liquid CPs near ambient conditions by introducing H₃PO₄ as a network modifier, shifting compositions away from stoichiometric ratios. This process disrupts extended coordination networks during melting, producing a stable

SUBMITTER: Ma N 

PROVIDER: S-EPMC12281088 | biostudies-literature | 2025 Jul

REPOSITORIES: biostudies-literature