Triazoles synthesis using nanocatalyst triazine-pyrimidine-modified cobalt-based metal-organic frameworks.

ABSTRACT: This research introduces a recyclable and environmentally friendly catalyst, Co(BDC-NH₂)-TA-PY, for the efficient synthesis of triazoles via the reaction of benzaldehydes, nitromethane, and sodium azide. The synthesis of Co(BDC-NH₂)-TA-PY was carried out through the post-synthetic modification of Co(BDC-NH₂), incorporating triazine-pyrimidine (TA-PY) functional groups. The key advantage of this catalyst lies in its dual functionality: the Lewis acidic sites of the Co(BDC-NH₂) metal-organic framework (MOF) are complemented by the Brønsted basic sites of the triazine and pyrimidine groups. This study represents the first example of a post-synthetic modification of the Co(BDC-NH₂) metal-organic framework (MOF) by integrating triazi

SUBMITTER: Amirian M 

PROVIDER: S-EPMC12301849 | biostudies-literature | 2025 Aug

REPOSITORIES: biostudies-literature