Photoredox-catalyzed arylation of isonitriles by diaryliodonium salts towards benzamides.

ABSTRACT: The arylation of isonitriles by diaryliodonium salts under photoredox conditions has been proposed for the first time. The suggested procedure allows preparing a broad range of benzamides using both symmetric and unsymmetric diaryliodonium salts under mild conditions. A plausible mechanism for the reaction and the selectivity of aryl transfer (in case of unsymmetrical iodonium salts) were studied.

SUBMITTER: Metalnikova NM 

PROVIDER: S-EPMC12302481 | biostudies-literature | 2025

REPOSITORIES: biostudies-literature