Synthesis, characterization, crystal engineering, DFT, and biological evaluation of a novel Cu(II)-perchlorate Schiff base complex.

ABSTRACT: Today's crystal engineering in coordination chemistry community offers diverse applications and innovative bonding concepts in crystal assembly. The current research delves into synthesizing one novel Cu(II) complex, [(NO₃)Cu(H₂O)(L^2,2-Me2)(μ-H₂O)Cu(L^2,2-Me2)](H₂O)ClO₄ (L^2,2-Me2 = Schiff base) with NaClO₄. A combination of standard spectroscopic methods, including SEM-EDX, XPS, and SCXRD (single-crystal X-ray diffraction) study, was used to characterize the complex. The X-ray structure reveals that the di-nuclear Cu(II) complex crystallizes in the triclinic space group P-1, and the crystal assembly is stabilized predominantly by C-H···π interactions, as well as hydrogen bonding interactions s

SUBMITTER: Majumdar D 

PROVIDER: S-EPMC12312248 | biostudies-literature | 2025 Jul

REPOSITORIES: biostudies-literature