Synthesis and crystal structures of 6- and 8-methyl-3-phenyl-benzo[<i>e</i>][1,2,4]triazines.

ABSTRACT: The synthesis and single-crystal X-ray structures of two regioisomeric Blatter radical precursors, 6-methyl-3-phenyl-benzo[e][1,2,4]triazine, (I), and 8-methyl-3-phenyl-benzo[e][1,2,4]triazine (II), C₁₄H₁₁N₃, are reported. Both compounds feature planar heteroaromatic frameworks with extensive π-conjugation across the benzo[e][1,2,4]triazine core. Compound I crystallizes in the ortho-rhom-bic space group Pbca, while II adopts the monoclinic space group P2₁/c. Structural analysis reveals nearly identical bond lengths and angles across both isomers, indicating minimal influence of methyl substitution on core geometry. Supra-molecular features are dominated by π-π stacking inter-ac

SUBMITTER: Constantinides CP 

PROVIDER: S-EPMC12326496 | biostudies-literature | 2025 Aug

REPOSITORIES: biostudies-literature