Synthesis, structure, catalytic and cytotoxic activities of chlorido-(5-nitro-quinolin-8-olato-κ² <i>N</i>,<i>O</i>)(tri-cyclo-hexyl-phosphine-κ<i>P</i>)platinum(II).

ABSTRACT: The title complex, [Pt(C₁₀H₅N₂O₃)Cl(C₁₈H₃₃P)], was synthesized by the reaction of [PtCl(C₁₀H₅N₂O₃)(η²-C₂H₄)] and PCy₃ at room temperature for 2 h with a yield of 80%. The deprotonated 5-nitro-quinoline-8-ol (C₁₀H₅N₂O₃ ^-) anion coordinates to the metal atom in a bidentate mode via its N and O atoms with a N-Pt-O bite angle of 80.0 (3)°. The tri-cyclo-hexyl-phosphine P atom is in a trans position with respect to the N atom in the square-planar coordination environment of the metal atom. The packing features zigzag chains linked by C-H⋯O inter-actions and continuous channel

SUBMITTER: Chi NTT 

PROVIDER: S-EPMC12326502 | biostudies-literature | 2025 Aug

REPOSITORIES: biostudies-literature