Iso-propyl-ammonium halidometallates. I. [Co<i>X</i> ₄]^2-·<i>X</i> ^- (<i>X</i> = Cl, Br), ZnCl₄ ^2-, and [ZnCl₃ ^-] _<i>n</i> salts.

ABSTRACT: An exploration of the iso-propyl-ammonium (IPA⁺) metal halide structural space is conducted, initially, for cobalt(II) and zinc(II) halides as a counterpart to the more extensively studied metal halide systems containing the isomeric tri-methyl-ammonium cation. For cobalt(II) halides, the only compound obtained from slow evaporation of acidic aqueous solutions of iso-propyl-ammonium halide and cobalt(II) halide is (IPA⁺)₃CoX ₄·X (X = Cl, Br), namely, tris-(iso-propyl-ammonium) tetra-chlorido-cobaltate(II) chloride, (C₃H₁₀N)₃[CoCl₄]Cl, and tris-(iso-propyl-ammonium) tetra-bromido-cobaltate(II) bromide, (C₃H₁₀N)₃[CoBr₄]Br, regardless of the

SUBMITTER: Birke J 

PROVIDER: S-EPMC12326503 | biostudies-literature | 2025 Aug

REPOSITORIES: biostudies-literature