Insight into the Carbon Monoxide Reduction Reaction on Cu(111) from Operando Electrochemical X-ray Photoelectron Spectroscopy.

ABSTRACT: In this work, we introduce a modified dip-and-pull electrochemical X-ray photoelectron spectroscopy (ECXPS) approach that offers new mechanistic insight into the alkaline carbon monoxide reduction reaction (CORR) over a Cu(111) single crystal surface. We tackle two major unresolved questions in the CORR mechanism that persist in the literature. Firstly, we address the mechanism for methane formation on Cu(111) and show that the mechanism likely proceeds via atomic carbon, which subsequently couples, leading to the accumulation of amorphous carbon on the surface. Secondly, we provide insight into whether the mechanism for acetate formation occurs entirely on the surface or partially within the solution phase, showing that acetate is present on the surface, indicating a surface-based reactio

SUBMITTER: Davies B 

PROVIDER: S-EPMC12338443 | biostudies-literature | 2025 Aug

REPOSITORIES: biostudies-literature