Designing supramolecular pastes by controlling host-guest dynamics in reconfigurable networks.

ABSTRACT: Stimuli-responsive phase transitions endow smart systems with adaptive functionalities, yet reversible paste-to-gel transitions remain largely unexplored. Here, we report a protonated trianglamine (TA)-based supramolecular paste, in which competitive supramolecular interactions-host-guest binding and electrostatic forces-drive the formation of a dynamic TA-clay-polymer ternary network with paste-like rheology. The material exhibits reversible paste-to-gel transitions under mild thermal stimuli, enabling shape reprogramming, temperature-triggered self-healing, and shape fixation. DFT calculations and molecular simulations reveal the molecular basis of the host-guest interactions in guiding network dynamics and healing behavior. Furthermore, incorporating graphene as conductive filler render

SUBMITTER: Wang J 

PROVIDER: S-EPMC12356893 | biostudies-literature | 2025 Aug

REPOSITORIES: biostudies-literature