Facet-Controlled Growth of Molybdenum Phosphide Single Crystals for Efficient Hydrogen Peroxide Synthesis.

ABSTRACT: Transition metal phosphides (TMPs) stand out for their excellent catalytic activity, driven by metal‒phosphorus bonding that promotes electron donation, which makes them ideal for electrocatalysis applications. However, the synthesis of single-crystal TMP, which is essential for elucidating intrinsic properties, remains challenging owing to the lack of efficient methods, low yields, and lengthy processes. This study presents the synthesis of facet-controlled molybdenum phosphide (MoP) single crystals using a liquid-metal-assisted chemical vapor deposition method. By adjusting the synthesis temperature, two distinct MoP morphologies are created: nanoplates dominated by (0001) facets and pillars dominated by (101¯0)$( {10\bar 10} )$ facets. Electrochemical evaluation reveals that the MoP pil

SUBMITTER: Kim SH 

PROVIDER: S-EPMC12392870 | biostudies-literature | 2025 Aug

REPOSITORIES: biostudies-literature