Investigation on Reactivity and Selectivity of Electrocatalytic CO₂ Reduction in Photochemically Synthesized Ag₁₉ and Alloyed Ag₁₉Cu₂ and Ag₁₂Cu₇ Nanoclusters.

ABSTRACT: Atomically precise nanoclusters are desirable for understanding the structure-property relationships in the electrocatalytic CO₂ reduction reaction (eCO₂RR), but suitable related models are lacking, especially those of low- or zerovalent noble metal nanoclusters and their alloyed analogues. We first developed a photochemical method toward silver nanocluster Ag₁₉(4- ^t BuPhC≡C)₁₄(Dpppe)₃(SbF₆)₃ (Ag ₁₉ -2e) and then related copper-doped alloyed nanocluster Ag₁₂Cu₇(4- ^t BuPhC≡C)₁₄(Dpppe)₃Cl₃(SbF₆)₂ (Ag ₁₂ Cu ₇ -0e). Her

SUBMITTER: Wang YX 

PROVIDER: S-EPMC12395295 | biostudies-literature | 2025 Aug

REPOSITORIES: biostudies-literature