Ion-Pairing Assemblies of Polarized Charged Porphyrin.

ABSTRACT: A porphyrin Au^III complex comprising 5,10-penatafluorophenyl units was synthesized as a dipolar π-electronic cation. The π-electronic cation was combined with anions, including a bulky borate anion and planar π-electronic anions. The dipolar π-electronic cation formed crystal-state ion-pairing assemblies based on antiparallel stacking structures, which were stabilized by interionic dipole-dipole interactions.

SUBMITTER: Kitayama R 

PROVIDER: S-EPMC12405815 | biostudies-literature | 2025 Sep

REPOSITORIES: biostudies-literature