Unraveling Unsupported Gold···Platinum Metallophilic Interactions: An In-Depth Computational and Topological Study.
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ABSTRACT: We have computationally studied the attraction between gold and platinum atoms in a series of unsupported model systems with formulas cis/trans-[Pt(CH3)2(NH3)2][Au(CH3)3(NH3)] (1a/1b), cis/trans-[Pt(CH3)2(NH3)2][Au(CH3)(NH3)] (2a/2b), [Pt(CH3)(NH3)3][Au(CH3)2] (3), and {[Pt(NH3)4][Au(CH3)2]}+ (4). These systems stem from the simplification of the well-known orthometalated complexes of these metals, allowing for a clearer-as-possible description of the metallophilic interaction while red
SUBMITTER: Reboiro F
PROVIDER: S-EPMC12406201 | biostudies-literature | 2025 Sep
REPOSITORIES: biostudies-literature
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