Ambient-Pressure Superconductivity Onset at 10 K and Robust T_c under High Pressure in TiNbTaN₃ Medium-Entropy Nitride.

ABSTRACT: Superconductivity has been one of the focal points in medium- and high-entropy alloys (MEAs-HEAs) since the first discovery of the HEA superconductor in 2014. Until now, most HEAs' superconducting transition temperature (T_c) has not exceeded 10 K. Here, the first observation of superconductivity in a bulk medium-entropy nitride (MEN), TiNbTaN₃, which shows a T_c of 10 K at ambient pressure, is reported. Notably, the electronic specific heat coefficient γ(H) exhibits nonlinear H-dependence behavior, which is similar to other well-studied multigap superconductors. Furthermore, TiNbTaN₃ exhibits extraordinary pressure resilience, maintaining robust superconductivity under high-pressure conditions. Density functional theory (DFT) calculations indicate that press

SUBMITTER: Zeng L 

PROVIDER: S-EPMC12407338 | biostudies-literature | 2025 Aug

REPOSITORIES: biostudies-literature