Crystal Growth Modulation of Tin-Lead Halide Perovskites via Chaotropic Agent.

ABSTRACT: Mixed tin-lead (Sn-Pb) halide perovskites, with their tunable bandgaps (1.2-1.4 eV), show great promise for the development of highly efficient all-perovskite tandem solar cells. However, achieving commercial viability and stabilized high efficiency for Sn-Pb perovskite solar cells (PSCs) presents numerous challenges. Among various optimization strategies, the incorporation of additives has proven critical in modulating the crystallization of Sn-Pb perovskites. Despite the widespread use of additives to improve performance, detailed photophysical mechanisms remain unclear. In this work, we elucidate the mechanistic role of guanidinium thiocyanate, a chaotropic agent, in the crystallization of Sn-Pb perovskites. We combine hyperspectral imaging with real-time in situ photoluminescence spect

SUBMITTER: Dong Y 

PROVIDER: S-EPMC12412113 | biostudies-literature | 2025 Sep

REPOSITORIES: biostudies-literature