Bis[1,2-bis-(4-fluoro-phen-yl)ethyl-ene-1,2-di-thiol-ato(1-)]nickel(II).

ABSTRACT: The crystal structure of the title compound, [Ni(C₁₄H₈F₂S₂)₂] (I), reveals averaged S-C [1.708 (2) Å] and C-C_chelate [1.395 (4) Å] bond lengths that are consistent with radical monoanionic ligands paired with a divalent Ni²⁺ ion. Mol-ecules of I associate as dyads via inter-molecular Ni⋯S close contacts of 3.396 (2) Å. This close association is enabled by a bending of both di-thiol-ene ligands to the same side and away from the NiS₄ planar inter-ior such that the angle between the seven atom mean planes defined by each NiS₂C₂ ring and the first C atom of each aryl substituent is 22.91 (8)°. These dyads form sheets in the bc plane that are held together i

SUBMITTER: Donahue JB 

PROVIDER: S-EPMC12412703 | biostudies-literature | 2025 Sep

REPOSITORIES: biostudies-literature