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Colloidal synthesis of ultrathin KFeS<sub>2</sub> and RbFeS<sub>2</sub> magnetic nanowires with non-van der Waals 1D structures.


ABSTRACT: Design of one-dimensional (1D) nanomaterials based on non-van der Waals (non-vdW) 1D chain structures is emerging as a new materials frontier, owing to their strong intrinsic anisotropy and broad compositional diversity. However, achieving ultrathin 1D morphology in such systems remains a significant challenge. In this work, we report the colloidal synthesis of ultrathin KFeS2 and RbFeS2 nanowires-representing the first fabrication of ultrathin 1D nanomaterials driven by non-vdW 1D crystal structures. The nanowires exhibit diameters of ∼5 nm and lengths of microns, with anisotropic growth directed by covalent [FeS2]- chains. Magnetic characterization reveals significantly reduced antiferromagnetic transition temperatures and suppressed interchain

SUBMITTER: Sun Z 

PROVIDER: S-EPMC12428650 | biostudies-literature | 2025 Sep

REPOSITORIES: biostudies-literature