Fine Tuning of the Redox-Active Diguanidine Ligand in Cationic Cobalt Complexes for Electronic Structure Control.

ABSTRACT: In this work we show that the redox chemistry of hexacoordinated cobalt complexes with redox-active diguanidine ligands could be tuned by modifying the diguanidine and/or the co-ligands. In this way, one-electron oxidation could be directed to be either ligand- or metal-centered, leading to high-spin Co^II complexes with an oxidized, radical-monocationic diguanidine ligand (ligand-centered oxidation) or low-spin Co^III complexes with a reduced, neutral diguanidine ligand. Further fine-tuning of the redox-active diguanidine ligand leads to a harmonization of the energies of both redox isomers. Consequently, ligand- as well as metal-centered one-electron oxidation is observed, resulting in a mixture of both redox isomers. Quantum-chemical calculations confirm the energeti

SUBMITTER: Osterbrink J 

PROVIDER: S-EPMC12434436 | biostudies-literature | 2025 Sep

REPOSITORIES: biostudies-literature