Optimization of thermoelectric performance in Sm-substituted SrSi₂ via carrier transport and lattice engineering.

ABSTRACT: The pursuit of sustainable thermoelectric materials requires the development of cost-effective and efficient compounds derived from earth-abundant elements. Here, we investigate the effects of samarium (Sm) substitution on the thermoelectric performance of SrSi₂ with compositions Sr_1-x Sm _x Si₂ (x = 0, 0.05, 0.1, 0.15, and 0.2). Substituting Sm for Sr in SrSi₂ enhances the power factor at low substitution levels, while further substitution leads to a decrease, due to increased carrier scattering and reduced Seebeck coefficient. Introducing Sm substitution enhances phonon scattering through point defects, reducing lattice thermal conductivity. A peak figure of merit (ZT) of ~0.23 at room temperature is achieved for Sr₀.₉₅Sm₀.₀₅Si₂

SUBMITTER: Trivedi V 

PROVIDER: S-EPMC12447468 | biostudies-literature | 2025

REPOSITORIES: biostudies-literature