Highly Selective Adsorption of Para-Xylene, Ethylbenzene, and Explicit Exclusion of Ortho-Xylene from Xylene Isomers Using a Pillar-Layered MOF with Tuned Pore Channels.

ABSTRACT: Xylene isomer separation is a long-standing challenge due to the nearly identical properties of para-xylene (PX), meta-xylene (MX), ortho-xylene (OX), and ethylbenzene (EB). Here, we report a rationally designed pillar-layered metal-organic framework (MOF), Ni-HDB, incorporating a cylindrical 1,4-diazabicyclo[2.2.2]octane (DABCO) pillar that blocks lateral channels and directs molecular transport through elliptical windows (3.2 × 6.7 Å²). These apertures closely match the dimensions of PX and EB, enabling kinetic sieving. As a result, Ni-HDB exhibits high selectivity for PX and EB, moderate selectivity for MX, and exclusion of OX under ambient conditions. It achieves record liquid-phase selectivities for EB/OX (1943), PX/OX (951), and MX/OX (158), along with high PX and MX adsor

SUBMITTER: Lee S 

PROVIDER: S-EPMC12455432 | biostudies-literature | 2025 Sep

REPOSITORIES: biostudies-literature