Arrested Cooperative Electron Transfer by Stabilization of a Long-Lived Confined Unpaired Electron.

ABSTRACT: Cooperative multielectron transfer is central to electron storage strategies and small-molecule activation and involves a thermodynamically favored second electron transfer occurring after the first electron transfer. This is the trademark of molecular systems with inverted redox potentials, but it is counterintuitive from an energetic point of view, and the nature of the transient intermediates involved has remained elusive. Using a nickel complex with inverted redox potentials, we show that a weakly coordinating anion (WCA), such as BAr^F ₄ ^- ([B-(C₆H₃(CF₃)₂)₄]^-), can act as a kinetic trap for the second electron to be transferred. Combined electrochemistry, UV-visible spectroscopy, advanced

SUBMITTER: Hessin C 

PROVIDER: S-EPMC12458033 | biostudies-literature | 2025 Sep

REPOSITORIES: biostudies-literature