Rationally Engineered Heterometallic Metalladithiolene Coordination Nanosheets with Defined Atomic Arrangements.

ABSTRACT: Coordination nanosheets are 2D polymers formed by coordination bonds between metal ions and planar organic molecules. They offer high molecular design freedom and unique electronic and chemical properties, making them suitable for various usage. In the two-phase interfacial reaction of metal ions with benzenehexathiol (BHT), highly conductive coordination nanosheets are generated. For nickel ions, porous NiDT (=Ni₃BHT₂) and nonporous NiBHT (=Ni₃BHT) structures are obtained. However, a rational selective synthesis method for these structures is not well-developed. In this study, selective synthesis of NiDT and NiBHT colloidal solutions is achieved by adjusting the BHT to metal ion ratio in a single phase. These colloidal solutions serve as hydrogen evolution

SUBMITTER: Ito M 

PROVIDER: S-EPMC12462590 | biostudies-literature | 2025 Sep

REPOSITORIES: biostudies-literature