Magnetically Induced Iron-Catalyzed Hydrodeoxygenation of Benzylic Esters and Polyesters.

ABSTRACT: The selective hydrodeoxygenation of benzylic esters with molecular hydrogen (H₂) provides a synthetic approach to methyl-substituted aromatic compounds used widely as intermediates and products in the chemical and pharmaceutical industries in accordance with green chemistry principles. In particular, it can open novel pathways for the use of biomass-derived substrates or waste plastics as chemical feedstocks. We present here an efficient catalytic approach focusing on the use of earth abundant iron in the form of iron carbide nanoparticles (ICNPs) activated by magnetic induction, allowing the reaction to proceed at pressures of only 3 bar of H₂. The activity of the ICNPs responds in real time to on/off switches of the alternating current magnetic field (ACMF, 350 kHz,

SUBMITTER: Ahmedi S 

PROVIDER: S-EPMC12464968 | biostudies-literature | 2025 Sep

REPOSITORIES: biostudies-literature