Spin-polarized Acidic Water Electrolysis with Antenna-Reactor Plasmonic Electrocatalysts.

ABSTRACT: Water electrolysis, driven by renewable electricity, offers a sustainable path for hydrogen production. However, efficient bifunctional electrocatalysts are needed to overcome the high overpotentials of both the oxygen evolution reaction and hydrogen evolution reaction. To address this, a novel catalyst system is developed integrating plasmonic nanoreactors with chirality-induced spin selectivity. In this system, chiral Au nanoparticles act as antennae, while single-atom iridium serves as the catalytic reactor, achieving a 3.5 fold increase in reaction kinetics (at 1.57 V vs RHE) compared to commercial IrO₂ catalysts and enhancing durability by over 4.8 times relative to conventional Pt/C || IrO₂ systems. Density functional theory and operando X-ray absorption spectro

SUBMITTER: Chae K 

PROVIDER: S-EPMC12506622 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature