Non-Bonded Interaction Driven Morphology Evolution of CuMOF@MXene Energetic Composites: Synergistic Optimization of Thermal Stability and Combustion Performance.

ABSTRACT: Hybrid materials with tunable properties, particularly metal-organic frameworks (MOFs)@MXene composites have emerged as a cutting-edge research focus different applications. In this study, a novel energetic CuMOF composed of Cu²⁺ and 3-(tetrazol-5-yl) triazole is synthesized, followed by the development of CuMOF@MXene composites (CuMOF@MXx) via a facile one-step hydrothermal method. This approach leverages the interfacial "Ti─O···Cu" non-bonded interactions to achieve composites with diverse morphologies. Subsequently, both experiments and theoretical calculations verify the presence of these non-bonded interactions and their influence on morphology, thermal property, and combustion performance of the composites. The morphologies of composites transition from a flower-like struc

SUBMITTER: Meng KJ 

PROVIDER: S-EPMC12520471 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature