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The Synthesis of Novel Glucosylamide Organosilicon Quaternary Ammonium Salts and Long-Lasting Modification of Different Materials.


ABSTRACT: Using renewable D-gluconic acid δ-lactone as the starting material, two novel glucosamide-based organosilicon quaternary ammonium surfactants (2/3SiDDGPBH) were synthesized through an environmentally friendly three-step process involving amidation, hydrophobic modification, and quaternization. Comprehensive characterization demonstrated their exceptional performance: surface tension reduction to 33.4 mN/m (2SiDDGPBH) and 33.64 mN/m (3SiDDGPBH), uniform spherical micelles (1-10 nm and 30-100 nm) were formed, and outstanding foam properties with 3SiDDGPBH developed, showing superior foamability and stability. Material modification tests on polymethyl methacrylate (PMMA) plates, mature acacia leaves, oilpaper, vegetable-tanned top-grain leather, and melamine-formal

SUBMITTER: Meng X 

PROVIDER: S-EPMC12525607 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature