Isopropanol Electro-Oxidation on PtCu Alloys for Aqueous Organic Redox Chemistry Toward Energy Storage.

ABSTRACT: Integration of renewable energy into modern power grids remains limited by intermittency and the need for reliable energy storage. Redox flow batteries (RFBs) are promising for large-scale energy storage, yet their widespread adoption is hindered by the high cost. In this study, we investigate isopropanol as a redox-active species with Pt-Cu alloy electrocatalysts for aqueous-organic RFBs. A series of Pt_xCu catalysts with varying Pt:Cu ratios were synthesized and studied for isopropanol electro-oxidation reaction (IPAOR) performance. Among them, PtCu demonstrated the best performance, achieving a low activation energy of 14.4 kJ/mol at 0.45 V vs. RHE and excellent stability at 1 M isopropanol (IPA) concentration. Kinetic analysis and in situ attenuated total reflectance-Fourier

SUBMITTER: Tang J 

PROVIDER: S-EPMC12525896 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature