Local Strain Tuning in Cu Nanoparticles through Glucose-Mediated Synthesis.

ABSTRACT: Cu nanoparticles are widely used in different fields. Controlling the Cu oxidation state and the local strain is fundamental for optimizing its efficiency in processes, such as catalytic reactions. In this work, Cu nanoparticles were synthesized by using glucose as a reducing agent. Different synthesis conditions led to nanoparticles with a tunable local strain and Cu(0)/Cu₂O ratio. The amounts of Cu(0) and Cu₂O are directly related to the local strain in the nanoparticles. The lower amount of Cu(0) gives a longer Cu-Cu distance, and the lower amount of Cu₂O is associated with longer Cu-O distances. It can be attributed to the creation of interfacial strain at the Cu(0)/Cu₂O boundaries, as demonstrated by molecular dynamics simulations. Furthermo

SUBMITTER: Girotto GZ 

PROVIDER: S-EPMC12529391 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature