Investigation on the structural, optical, photoluminescence and electric properties of a semiconductor material [Br(CH<sub>2</sub>)<sub>2</sub>N(CH<sub>3</sub>)<sub>3</sub>]<sub>2</sub>SnBr<sub>6</sub>.
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ABSTRACT: A new low-dimensional hybrid tin(iv) halides, [Br(CH2)2N(CH3)3]2SnBr6, was synthesized via slow evaporation from acidic aqueous solution under ambient conditions. Single-crystal X-ray diffraction reveals that the compound crystallizes in the orthorhombic space group Pbca, featuring discrete [SnBr6]2- octahedra spatially isolated and electrostatically stabilized by [Br(CH2)2N(CH3)3]+ cations. The crystal packing is reinforced through a network of C-H⋯Br hydrogen bonds and halogen···halogen contacts, forming a 0D supramolecular framework. Infrared spectroscopy confirms the existence of characteristic vibrational modes from organic molecu
SUBMITTER: Elghoul A
PROVIDER: S-EPMC12542898 | biostudies-literature | 2025 Oct
REPOSITORIES: biostudies-literature
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