Lithium 2-trifluoromethyl-4,5-dicyanoimidazole (LiTDI) as an Alternative Salt for Aqueous Li-Ion Batteries.

ABSTRACT: Water-in-salt batteries have emerged as promising candidates for electrochemical storage systems, due to their enhanced safety and low cost compared to conventional Li-ion batteries. However, to date, they relied on very high salt concentrations (mostly LiTFSI salt), meaning that they remain an expensive solution for storage application. LiTDI has previously been reported to act as a water scavenger agent in organic-based electrolyte. Herein, a comprehensive investigation of LiTDI as a potential alternative salt for aqueous batteries is conducted. Although LiTDI exhibits lower electrochemical performance compared to LiTFSI, it enables high ionic conductivity at lower concentrations showing good ability for aqueous battery. Furthermore, it sustains an electrochemical stability window of ≈2.

SUBMITTER: Servajon P 

PROVIDER: S-EPMC12548938 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature