Ureas are identified as the first neutral O-donors broadly effective in stabilizing ionic liquids and other salts of boron-centred cations: synthesis and detailed characterization.

ABSTRACT: Stimulated by recent work showing them to be promising electrolytes in batteries and supercapacitors, and to have useful levels of antibacterial, antifungal, and antiviral activity, there is growing interest in salts of boron-centered cations - boronium ions. However, compared to the number of existing structural variants among molecular cations such as ammonium ions, that of boroniums is minescule. This likely stems from the narrow scope of Lewis base types - largely amines and N-heterocycles - known to stabilize cationic boron centres. We have now determined that ureas, in combination with amines, are effective in stabilizing boronium cations, greatly enhancing the scope of structural-geometric space which can be explored with these compounds. And, depending on the specific urea u

SUBMITTER: Crowley ME 

PROVIDER: S-EPMC12557308 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature