Efficient and Selective Photocatalytic Transformation of CO₂ to CO with Mo₆ Clusters Supported on Fe-Doped g‑C₃N₄.

ABSTRACT: The carbon dioxide reduction reaction (CO₂RR) driven by sunlight is expected to become a sustainable way of producing high-value compounds in the future. To achieve this goal, affordable and efficient photocatalysts still need to be discovered. In this work, we show that near-IR luminescent octahedral molybdenum iodido clusters decorated with isonicotinato ligands, (Bu₄N)₂[Mo₆I₈(O₂CC₅H₄N)₆] (Mo₆), once combined with iron-doped carbon nitride (Fe-g-C₃N₄), provide the Mo₆/Fe-g-C₃N₄ nanostructured materials, which are able to photocatalytically produce carbon monoxide (CO) from CO₂ with high efficiency and

SUBMITTER: Hernandez JS 

PROVIDER: S-EPMC12570109 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature