Efficient and Selective Photocatalytic Conversion of Low-Concentration CO₂ to CO Using Mn-Complex Catalysts.

ABSTRACT: For the practical application of photocatalytic CO₂ reduction systems, it should be important that the catalyst directly reduces low concentrations of CO₂ in photocatalytic systems consisting of only Earth-abundant elements. Despite the development of numerous photocatalytic CO₂ reduction systems, CO₂ utilization at low CO₂ concentrations has not been thoroughly investigated. Although fac-[Mn^I(diimine)(CO)₃L]ⁿ⁺-type complexes are among the most abundant transition-metal complexes and have been studied as CO₂ reduction catalysts in electrocatalytic systems, their application in photocatalytic reactions has been limited by the formation of photochemically unstable Mn(0) dimers. Th

SUBMITTER: Kamogawa K 

PROVIDER: S-EPMC12576768 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature