Continuous-Wave (CW) Photo-CIDNP NMR Spectroscopy: A Tutorial.

ABSTRACT: Photo-chemically induced dynamic nuclear polarisation (photo-CIDNP) is a nuclear spin-selective magnetic resonance phenomenon that has traditionally been used to mechanistically study chemical reactions involving the (transient) formation of radical molecular species, extract EPR observables of short-lived radicals, probe biomolecular structure and interactions and, less importantly, increase the sensitivity of a nuclear magnetic resonance (NMR) measurement. Recently, the introduction of significant methodological advances as well as the advent of benchtop NMR spectroscopy has rekindled interest in this technique, which-serendipitously discovered more than half a century ago-has, as of late, matured into a powerful, highly sensitive and extremely versatile NMR hyperpolarisation method. In

SUBMITTER: Kuhn LT 

PROVIDER: S-EPMC12583242 | biostudies-literature | 2025 Dec

REPOSITORIES: biostudies-literature