Syntheses and structures of a nitro-gen-rich pyrimidine triazole ligand and its Cu^I and Ag^I complexes.

ABSTRACT: The product of an azide-alkyne Huisgen cyclo-addition between a pyridine azide and a simple alkyne was crystallized alongside the products of the corresponding complexation reactions with copper(I) iodide and silver(I) nitrate. 4,6-Di-meth-yl-2-(4-propyl-1H-1,2,3-triazol-1-yl)pyrimidine, C₁₁H₁₅N₅, crystallizes with three mol-ecules in the asymmetric unit. The extended structure involves aromatic π-stacking and an extensive network of C-H⋯N hydrogen bonds. The copper complex, di-μ-iodido-bis-{[4,6-dimethyl-2-(4-propyl-1H-1,2,3-triazol-1-yl-κN ²)pyrimidine-κN ¹]copper(I)}, [Cu₂I₂(C₁₁H₁₅N₅)₂], is dimeric with a pair of bridging iodide ions and

SUBMITTER: Webb DJ 

PROVIDER: S-EPMC12589829 | biostudies-literature | 2025 Nov

REPOSITORIES: biostudies-literature