Syntheses and structures of two anthracene-benzoic acid derivatives as potential MOF linkers.

ABSTRACT: In the title compounds, 2,2'-{[anthracene-9,10-diylbis(methyl-ene)]bis-(sulfane-di-yl)}di-benzoic acid di-methyl-acetamide tetra-solvate, C₃₀H₂₂O₄S₂·4C₄H₉NO 1 and 4,4'-{[anthracene-9,10-diylbis(methyl-ene)]bis-(-oxy)}di-benzoic acid di-methyl-formamide disolvate, C₃₀H₂₂O₆·2C₃H₇NO 2, the complete anthracene-benzoic acid mol-ecule is generated by a crystallographic centre of symmetry. The dihedral angle between the anthracene ring system and the pendant ring is 71.43 (7) in 1 and 75.27 (12)° in 2. In the extended structures of 1 and 2, O-H⋯O hydrogen bonds link the main mol-ecules into pairs of solvent mol-ecules to generate trimer

SUBMITTER: Kushwaha S 

PROVIDER: S-EPMC12589845 | biostudies-literature | 2025 Nov

REPOSITORIES: biostudies-literature