Versatility of the methyl-bipyrimidine-<i>N</i>-oxide ligand for the design of lanthanide single-molecule magnets.

ABSTRACT: A library of ten complexes, [Yb₂(hfac)₆(L)] (1), [Yb₆(hfac)₁₄(OH)₄(L)₂] (2), [Dy(hfac)₃(L)]₂·C₂H₄Cl₂ ((3)·C₂H₄Cl₂), [Dy(hfac)₃(L)]₂[Dy(hfac)₃(H₂O)₂] (4), [Dy₆(hfac)₁₄(OH)₄(L)₂] (5), [Yb(tta)₃(L)] (6) and [Ln₂(hfc)₆(L)] (Ln = Dy ((-)7, (+)7) and Yb ((-)8, (+)8)) (where hfac^- = 1,1,1,5,5,5-hexafluoroacetylacetonate, tta^- = 2-thenoyltrifluoroacetylacetonate, hfc^- = 3-(heptafluoropropylhydroxymethylene-(±)-camphorate and L = 4-methylbipyrimidine-2-N<

SUBMITTER: Douib H 

PROVIDER: S-EPMC12593191 | biostudies-literature | 2025 Dec

REPOSITORIES: biostudies-literature