2-Fluoro-benzyl (<i>Z</i>)-2-(5-chloro-2-oxoindolin-3-yl-idene)hydrazine-1-carbodi-thio-ate dimethyl sulfoxide monosolvate.

ABSTRACT: In the title solvate, C₁₆H₁₁ClFN₃OS₂·C₂H₆OS, the C=N bond adopts a Z-configuration facilitating the formation of an intra-molecular N-H⋯O hydrogen bond to the carbonyl O atom in an S(6) loop. The di-methyl-sulfoxide solvent mol-ecule accepts a strong discrete N-H⋯O hydrogen bond from the γ-lactam grouping. In the extended structure, C_ar-H⋯S hydrogen bonds and quasi-Type I/II Cl⋯F halogen⋯halogen bonds are observed, while adjacent dimethyl sulfoxide mol-ecules form S⋯O chalcogen-bonded chains.

SUBMITTER: McKay AP 

PROVIDER: S-EPMC12598888 | biostudies-literature | 2025 Oct

REPOSITORIES: biostudies-literature